韩露
,
刘春立
,
王影
,
谢国君
,
卢克非
宇航材料工艺
doi:10.3969/j.issn.1007-2330.2014.06.015
分离装置静力试验后发现连接两个舱体的双头螺栓中有7件发生断裂,螺栓表面进行了达克罗处理.通过失效分析及相关试验综合分析认为,分离装置上7件螺栓的断裂性质均为延迟性脆性断裂,断裂机理为氢脆.导致发生氢脆断裂的原因除螺栓材料及组织具有较高的氢脆敏感性外,主要与静力试验过程中长时间包覆湿泥有关;另外,原材料氢含量控制及达克罗涂层工艺处理虽然有效避免了产品表面处理过程中带来的氢脆隐患,但是若使用环境中存在水及腐蚀性介质Cl、S时,产品在拉应力作用下仍可能发生氢脆延迟断裂而导致严重后果.
关键词:
30CrMnSiNi2A
,
双头螺栓
,
达克罗
,
氢脆
,
电化学腐蚀
Min SUN
金属学报(英文版)
The electrochemical corrosion behavior of 300M ultra high strength steel in chloride containing environment was investigated by potentiodynamic polarization technique, electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM). The results show that uniform corrosion occurs on 300M steel during the electrochemical measurements because no anodic passivation phenomenon is observed on polarization curves within the measurement range. The tests also show that 300M steel is highly susceptible to chloride containing solution, which is characterized by corrosion current density increasing with the addition of chlorides, and corrosion potential shifting towards positive direction and corrosion resistance decreasing, positively suggesting that chloride ions speed up the corrosion rate of 300M steel. Meanwhile corrosion products on the 300M steel surface formed during the salt spray test are too loose and porous to effectively slow down the corrosion rate. Additionally, a schematic structure of uniform corrosion mechanism can explain that 300M steel has better property of stress corrosion cracking (SCC) resistance than stainless steels.
关键词:
300M ultra high strength steel
,
electrochemical corrosion
,
chloride
